JEE Main & Advanced Chemistry Alcohols, Phenols and Ethers / एल्कोहॉल, फीनॉल तथा ईथर Question Bank Preparation of alcohol Phenol and Ethers

  • question_answer
    \[{{C}_{6}}{{H}_{5}}-CH=CHCHO\xrightarrow{X}{{C}_{6}}{{H}_{5}}CH=CHC{{H}_{2}}OH\]. In the above sequence X can be                 [DCE 2004]

    A)                 \[{{H}_{2}}/Ni\]               

    B)                 \[NaB{{H}_{4}}\]

    C)                 \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}/{{H}^{+}}\]            

    D)                 Both A and B

    Correct Answer: B

    Solution :

               \[NaB{{H}_{4}}\] and \[LiAl{{H}_{4}}\] attacks only carbonyl group and reduce it into alcohol group. They do not attack on double bond.                    \[\underset{\text{cinnamic aldehyde}}{\mathop{{{C}_{6}}{{H}_{5}}-CH=CHCHO}}\,\xrightarrow{NaB{{H}_{4}}}\]\[\underset{\text{cinnamic alcohol}}{\mathop{{{C}_{6}}{{H}_{5}}-CH=CH.C{{H}_{2}}OH}}\,\]


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