JEE Main & Advanced Chemistry Analytical Chemistry Question Bank Preliminary Test

  • question_answer
    \[Mn{{O}_{2}}\] and \[{{H}_{2}}S{{O}_{4}}\] added to \[NaCl\], the greenish yellow gas liberated is  [Orissa JEE 2005]

    A) \[C{{l}_{2}}\]

    B) \[N{{H}_{3}}\]

    C) \[{{N}_{2}}\]

    D) \[{{H}_{2}}\]

    Correct Answer: A

    Solution :

    Yellowish-green gas of chlorine with suffocating odour is evolved when the solid chloride mixed with manganese dioxide is heated with concentrated\[{{H}_{2}}S{{O}_{4}}\]. \[NaCl+{{H}_{2}}S{{O}_{4}}\to NaHS{{O}_{4}}+HCl\] \[Mn{{O}_{2}}+4HCl\to MnC{{l}_{2}}+2{{H}_{2}}O+C{{l}_{2}}\]


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