JEE Main & Advanced Chemistry Chemical Bonding and Molecular Structure / रासायनिक आबंधन एवं आणविक संरचना Question Bank Molecular orbital theory

  • question_answer
    Which of the following is paramagnetic  [MP PET 1999]

    A)                 \[{{O}_{2}}\]     

    B)                 \[C{{N}^{-}}\]

    C)                 \[CO\]  

    D)                 \[N{{O}^{+}}\]

    Correct Answer: A

    Solution :

               Electronic configuration of \[{{O}_{2}}\] is             \[{{O}_{2}}=\sigma {{(1s)}^{2}}{{\sigma }^{*}}{{(1s)}^{2}}\sigma {{(2s)}^{2}}{{\sigma }^{*}}{{(2s)}^{2}}\sigma {{(2{{p}_{x}})}^{2}}\pi {{(2{{p}_{y}})}^{2}}\]  \[\pi {{(2{{p}_{z}})}^{2}}{{\pi }^{*}}{{(2{{p}_{y}})}^{1}}{{\pi }^{*}}{{(2{{p}_{z}})}^{1}}\] The molecule has two unpaired electrons So, it is paramagnetic


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