JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Kp and Kc Relationship and Characteristics of K

  • question_answer
    For the reaction \[2N{{O}_{2(g)}}\]⇌ \[2N{{O}_{(g)}}+{{O}_{2(g)}}\] \[({{K}_{c}}=1.8\times {{10}^{-6}}\,\text{at}\,\,184{}^\circ C)\] \[(R=0.0831\,kJ/\,(mol.\,K))\] When \[{{K}_{p}}\] and \[{{K}_{c}}\] are compared at 184°C it is found that          [AIEEE 2005]

    A)                 \[{{K}_{p}}\] is greater than \[{{K}_{c}}\]

    B)                 \[{{K}_{p}}\] is less than \[{{K}_{c}}\]

    C)                 \[{{K}_{p}}={{K}_{e}}\]

    D)                 Whether \[{{K}_{p}}\] is greater than, less than or equal to \[{{K}_{c}}\] depends upon the total gas pressure

    Correct Answer: A

    Solution :

                \[{{k}_{p}}={{k}_{c}}{{(RT)}^{\Delta n}}\]                 \[\Delta n=3-2=1\];  \[{{k}_{p}}>{{k}_{c}}\].


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