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question_answer1)
Buna-N synthetic rubber is a copolymer of
A)
B)
C)
D)
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question_answer2)
Among cellulose, poly (vinyl chloride), nylon and natural rubber, the polymer in which the intermolecular force of attraction is weakest is
A)
nylon done
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B)
poly (vinyl chloride) done
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C)
cellulose done
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D)
natural rubber. done
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question_answer3)
Which of the following is used in vulcanization of rubber?
A)
\[S{{F}_{6}}\] done
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B)
\[C{{F}_{4}}\] done
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C)
\[C{{l}_{2}}{{F}_{2}}\] done
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D)
\[{{C}_{2}}{{F}_{2}}\] done
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question_answer4)
Formation of polyethylene from calcium carbide takes place as follows: \[Ca{{C}_{2}}+2{{H}_{2}}O\to Ca{{(OH)}_{2}}+{{C}_{2}}{{H}_{2}}\]\[{{C}_{2}}{{H}_{2}}+{{H}_{2}}\to {{C}_{2}}{{H}_{2}}\] \[n{{C}_{2}}{{H}_{2}}\to {{(-C{{H}_{2}}-C{{H}_{2}}-)}_{n}}\] The amount of polyethylene obtained from 64.1 kg of\[Ca{{C}_{2}}\] is
A)
7 kg done
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B)
4 kg done
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C)
21 kg done
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D)
28 kg done
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question_answer5)
Which of the following is resistant to boiling aqua regia?
A)
Polythene done
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B)
Perspex done
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C)
Teflon done
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D)
Bakelite done
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question_answer6)
In the process of forming 'mercerised cellulose' the swelling of cellulose is caused by
A)
Water done
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B)
\[N{{a}_{2}}C{{O}_{3}}\] done
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C)
conc.\[NaOH\] done
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D)
cone. \[HCl\] done
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question_answer7)
Which of the following sets contains only thermoplastics?
A)
PVC, PMMA, polystyrene done
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B)
Polythene, Bakelite, nylon-6 done
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C)
Glyptal, Melmac, PAN done
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D)
Polypropylene, urea-formaldehyde, Teflon done
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question_answer8)
Free radical polymerisation requires a free radical initiator. The most commonly used free radical initiator is
A)
B)
\[(C{{H}_{3}})C-O-O-C{{(C{{H}_{3}})}_{3}}\], tert-butyl peroxide done
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C)
\[Ph-CO-O-O-COPh\], benzoyl peroxide done
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D)
\[C{{H}_{2}}{{N}_{2}},\]diazomethane done
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question_answer9)
The polymerisation reaction shown below
would produce
A)
PVC done
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B)
neoprene done
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C)
chloroprene done
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D)
Rubber done
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question_answer10)
Which pair of polymers have similar properties?
A)
Nylon, PVC done
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B)
PCTFE done
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C)
PAN, PTFE done
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D)
Bakelite alkyl resin done
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question_answer11)
Which of the following monomers can undergo radical, cationic as well as anionic polymerisation with equal ease?
A)
B)
\[C{{H}_{2}}=CH-CH\] done
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C)
\[{{C}_{6}}{{H}_{5}}-CH=C{{H}_{2}}\] done
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D)
\[C{{H}_{2}}=C{{H}_{2}}\] done
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question_answer12)
What is not true regarding free radical polymerisation of propene?
A)
Without proper control, atactic polypropylene is produced done
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B)
During polymerization, a secondary free radical is produced in every step done
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C)
Use of Ziegler-Natta catalyst results in isotactic polypropylene done
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D)
During polymerization, a linear, unbranched, crystalline polymer is usually obtained done
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question_answer13)
Gutta-percha is
A)
trans-polyisoprene done
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B)
non-elastic and softens to a plastic ?like material on heating done
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C)
used in underwater cables and golf balls done
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D)
All of the above done
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question_answer14)
The number average molecular mass and mass average molecular mass of a polymer are respectively 30,000 and 40,000. The polydispersity index of the polymer is
A)
<1 done
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B)
>1 done
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C)
1 done
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D)
0 done
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question_answer15)
Nylon-6, 10 is prepared by the condensation polymerisation of
A)
adipic acid and hexamethylenediamine done
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B)
sebacic acid and hexamethylene-diamine done
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C)
sebacic acid and hexamethylene-amine done
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D)
none of the above done
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question_answer16)
Isotactic polypropylene polymer is one in which
A)
the methyl groups present alternate regularly from one side to the other done
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B)
all methyl groups are on one side of the extended chain. It is a highly crystalline, has high melting point and forms strong fibres done
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C)
the methyl groups are distributed at random. It is a soft, elastic and rubbery material done
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D)
None of the above done
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question_answer17)
Match the following
(i) | Biodegradable polymer | (p) | 3-Hydroxybutanoic acid |
(ii) | Bakelite | (q) | phenol |
(iii) | Neoprene | (r) | 2-chlorobuta-1, 3-diene |
(iv) | Glyptal | (s) | phthalic acid |
A)
i\[\to \]p; ii\[\to \]q; iii\[\to \]r; iv\[\to \]s done
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B)
i\[\to \]q; ii\[\to \]p; iii\[\to \]r; iv\[\to \]s done
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C)
i\[\to \]p; ii\[\to \]q; iii\[\to \]s; iv\[\to \]r done
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D)
i\[\to \]s; ii\[\to \]r; iii\[\to \]p; iv\[\to \]q done
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question_answer18)
Arrange the following monomers in order of decreasing ability to undergo cationic polymerisation. |
(I) \[C{{H}_{2}}=CH-{{C}_{6}}{{H}_{4}}(N{{O}_{2}})\] |
(II) \[C{{H}_{2}}=CH-{{C}_{6}}{{H}_{4}}(C{{H}_{3}})\] |
(III) \[C{{H}_{2}}=CH-{{C}_{6}}{{H}_{4}}(OC{{H}_{3}})\] |
A)
I > II > III done
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B)
II > I > III done
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C)
III > II > I done
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D)
I > III > II done
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question_answer19)
The compound required for the formation of a thermosetting polymer with methanal is
A)
benzene done
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B)
phenyl amine done
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C)
benzaldehyde done
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D)
phenol done
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question_answer20)
Which of the following is a biodegradable polymer?
A)
Cellulose done
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B)
Polythene done
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C)
Polyvinyl chloride done
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D)
Nylon-6 done
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question_answer21)
How many of the following is a condensation polymer? |
Polystyrene, |
Neoprene, |
PAN, |
Poly (ethyleneterephthalate) |
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question_answer22)
An acidic resin can be made by the polymerization of 4-vinylpyridine initiated by AIBN and heat followed by treatment of the polymer with bromoacetate. How many (C = C) bonds are in conjugation with each other in 4-vinylpyridine?
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question_answer23)
How many of the following are condensation copolymers? Nylon-6, Nylon-66, Dacron, Glyptal, buna-S, ABS, neoprene, PHBV, perlo U
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question_answer24)
In the formation of how many of the following there is no loss of small molecules? Orion, PTFE, neoprene, Bakelite, buna-S, Melmac, vinyon, ABS, SAN.
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question_answer25)
PDI for natural polymers is generally close to.........
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