JEE Main & Advanced Chemistry Coordination Chemistry Question Bank Isomerism and magnetic Properties

  • question_answer
    \[\left[ Co{{\left( N{{H}_{3}} \right)}_{4}}C{{l}_{2}} \right]N{{O}_{2}}\] and \[\left[ Co{{\left( N{{H}_{3}} \right)}_{4}}Cl.N{{O}_{2}} \right]Cl\] are ........ isomers [MP PMT 1993; MP PET 1995, 2001]

    A) Geometrical

    B) Optical

    C) Linkage

    D) Ionization

    Correct Answer: D

    Solution :

      Both produce different ions in solution state- \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\]  ⇌ \[{{[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]}^{+}}NO_{2}^{-}\] \[[Co{{(N{{H}_{3}})}_{4}}Cl.\,N{{O}_{2}}]Cl\]⇌\[{{[Co{{(N{{H}_{3}})}_{4}}Cl\,.\,N{{O}_{2}}]}^{+}}+C{{l}^{-}}\]


You need to login to perform this action.
You will be redirected in 3 sec spinner