A) \[{{V}_{m}}>22.4\]litres
B) \[{{V}_{m}}<22.4\]litres
C) \[{{V}_{m}}=22.4\]litres
D) \[{{V}_{m}}=44.8\]litres
Correct Answer: B
Solution :
Compressibility = \[\frac{PV}{nRT}<1\] at STP (as given) \[\left. \begin{align} & nRT>PV \\ & N\times 0.0821\times 273>1{{V}_{m}} \\ & 22.41\ litres>{{V}_{m}} \\ \end{align} \right\}\begin{matrix} R=\text{ }0.821 \\ T=\text{ }{{273}^{o}}K \\ P\text{ }=\text{ }1 \\ \end{matrix}\] n = 1
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