JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank Free energy and work function

  • question_answer
    At 300 K, the reactions which have following values of thermodynamic parameters occur spontaneously [Roorkee 1999]

    A)                 \[\Delta {{G}^{o}}=-400\,\,kJ\,\,mo{{l}^{-1}}\]

    B)                 \[\Delta {{H}^{o}}=200\,\,kJ\,\,mo{{l}^{-1}},\,\,\,\Delta {{S}^{o}}=-4\,\,J{{K}^{-1}}mo{{l}^{-1}}\]

    C)                 \[\Delta {{H}^{o}}=-200\,kJ\,mo{{l}^{-1}},\,\,\Delta {{S}^{o}}=4\,J{{K}^{-1}}mo{{l}^{-1}}\]

    D)                 \[\Delta {{H}^{o}}=200\,J\,mo{{l}^{-1}},\,\,\Delta {{S}^{o}}=40\,J{{K}^{-1}}mo{{l}^{-1}}\]

    Correct Answer: A

    Solution :

                    When \[\Delta H=+ve\] and \[\Delta S=-ve\] than the reaction is non-spontaneous.


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