JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank Free energy and work function

  • question_answer
    The free energy change for the following reactions are given below, \[{{C}_{2}}{{H}_{2}}(g)+\frac{5}{2}{{O}_{2}}(g)\,\to \]\[2C{{O}_{2}}(g)+{{H}_{2}}O(l);\,\Delta {{G}^{o}}=-1234\,kJ\] \[C(s)+{{O}_{2}}(g)\,\to C{{O}_{2}}(g)\,\,\Delta {{G}^{o}}=-394\,kJ\] \[{{H}_{2}}(g)+\frac{1}{2}{{O}_{2}}(g)\,\to \,{{H}_{2}}O(l)\,\,\,\Delta {{G}^{o}}=-237kJ\] What is the standard free energy change for the reaction \[{{H}_{2}}(g)+2\,C\,(s)\to {{C}_{2}}{{H}_{2}}(g)\]                                        [Kerala (Med.) 2002]

    A)                 ? 209 kJ

    B)                 ? 2259 kJ

    C)                 + 2259 kJ             

    D)                 209 kJ

    Correct Answer: D

    Solution :

           By 2× (ii) ? (i) ? (iii)                                 \[{{H}_{2(g)}}+2{{C}_{(s)}}\to {{C}_{2}}{{H}_{2(g)}},\,\,\,\Delta {{G}^{\circ }}=209\,kJ\].


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