JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी Question Bank First law of thermodynamics and Hess law

  • question_answer
    For which of the reaction \[\Delta H=\Delta E\]                  [MP PET 2004]

    A)                 \[{{N}_{2}}+3{{H}_{2}}\]⇌\[2N{{H}_{3}}\]      

    B)                 \[{{N}_{2}}+{{O}_{2}}\to 2NO\]

    C)                 \[2Na+C{{l}_{2}}\to 2NaCl\]       

    D)                 \[PC{{l}_{5}}\to PC{{l}_{3}}+C{{l}_{2}}\]

    Correct Answer: B

    Solution :

               \[{{N}_{2}}(g)+{{O}_{2}}(g)\to 2NO(g)\]; \[\Delta {{n}_{g}}=2-2=0\]                                 \[\Delta H=\Delta E+\Delta {{n}_{g}}RT\];  \[\Delta H=\Delta E+0\];  \[\Delta H=\Delta E\]


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