JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Question Bank Critical Thinking

  • question_answer
    The concentration of \[[{{H}^{+}}]\] and concentration of \[[O{{H}^{-}}]\] of a 0.1 aqueous solution of 2% ionised weak acid is [Ionic product of water \[=1\times {{10}^{-14}}]\] [DPMT 2004; CBSE PMT 1999]

    A)                 \[2\times {{10}^{-3}}\]M and \[5\times {{10}^{-12}}\]M

    B)                 \[1\times {{10}^{3}}\ M\ \text{and}\ 3\times {{10}^{-11}}M\]

    C)                 \[0.02\times {{10}^{-3}}\ M\ \text{and}\ 5\times {{10}^{-11}}M\]

    D)                 \[3\times {{10}^{-2}}\ M\ \text{and}\ 4\times {{10}^{-13}}M\]

    Correct Answer: A

    Solution :

               Given that                    Concentration of solution =.1                    Degree of ionisation \[=2%=\frac{2}{100}=.02\]                    Ionic product of water \[=1\times {{10}^{-14}}\]                    Concentration of \[[{{H}^{+}}]\]= Concentration of solution X degree of ionisation \[=.1\times .02=2\times {{10}^{-3}}M\]                    Concentration of \[[O{{H}^{-}}]=\frac{\text{Ionic product of water}}{[{{H}^{+}}]}\]                                 \[=\frac{1\times {{10}^{-14}}}{2\times {{10}^{-3}}}=0.5\times {{10}^{-11}}=5\times {{10}^{-12}}M\].


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