JEE Main & Advanced Chemistry GOC Question Bank Critical Thinking

  • question_answer
    \[S{{N}^{1}}\] reaction is faster in [Orissa JEE 2004]

    A) \[C{{H}_{3}}C{{H}_{2}}Cl\]

    B) \[\begin{matrix}    C{{H}_{3}}  \\    C{{H}_{3}}  \\ \end{matrix}>CH-Cl\]

    C) \[C{{H}_{3}}-\underset{C{{H}_{3}}\ }{\overset{C{{H}_{3}}\ }{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,-Cl}}}\,\]

    D) \[C{{H}_{3}}-\underset{C{{H}_{3}}}{\mathop{\underset{\underset{|}{\mathop{C}}\,{{H}_{2}}}{\mathop{\underset{|}{\mathop{C}}\,H\ }}\,}}\,-Cl\]

    Correct Answer: C

    Solution :

    \[S{{N}^{1}}\] mechanism proceeds through carbocation intermediate. \[C{{H}_{3}}-\underset{C{{H}_{3}}\ \,}{\overset{C{{H}_{3}}\ \ }{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,-Cl}}}\,\]


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