JEE Main & Advanced Chemistry Organic Chemistry: Some Basic Principles & Techniques / कार्बनिक रसायन : कुछ मूलभूत सिद्धांत एवं तकन Question Bank Critical Thinking

  • question_answer
    A hydrocarbon contains 10.5 gm carbon and 1gm hydrogen. Its 2.4 gm has 1 litre volume at 1 atm and \[{{127}^{o}}C\], hydrocarbon is [UPSEAT 2003]

    A) \[{{C}_{6}}{{H}_{7}}\]

    B) \[{{C}_{6}}{{H}_{8}}\]

    C) \[{{C}_{5}}{{H}_{6}}\]

    D) None of these

    Correct Answer: A

    Solution :

    \[C=10.5\,\,gm=\frac{10.5}{12}mol=0.87\,\,mol\] \[H=1\,\,gm=\frac{1}{1}=1\,\,mol\] \[\therefore \,{{({{C}_{0.87}}{{H}_{1}})}_{7}}={{C}_{6.09}}{{H}_{7}}\approx {{C}_{6}}{{H}_{7}}\] \[PV=nRT\];     \[PV=\frac{w}{m}RT\] \[1\times 1=\frac{2.4}{m}\times 0.082\times 400\] \[m=2.4\times 0.082\times 400\]\[=78.42\approx 79\].


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