JEE Main & Advanced Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank Compounds of Transitional Elements

  • question_answer
    Copper sulphate solution reacts with \[KCN\] to give [MP PMT 1992; MNR 1994; IIT 1996; AIIMS 1999; CBSE PMT 2002]

    A) \[Cu{{(CN)}_{2}}\]

    B) \[CuCN\]

    C) \[{{K}_{2}}[Cu{{(CN)}_{4}}]\]

    D) \[{{K}_{3}}[Cu{{(CN)}_{4}}]\]

    Correct Answer: D

    Solution :

      \[CuS{{O}_{4}}+2KCN\to Cu{{(CN)}_{2}}+{{K}_{2}}S{{O}_{4}}\] \[2Cu{{(CN)}_{2}}\to C{{u}_{2}}{{(CN)}_{2}}+{{(CN)}_{2}}\] \[C{{u}_{2}}{{(CN)}_{2}}+6KCN\to 2{{K}_{3}}[Cu{{(CN)}_{4}}]\]


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