JEE Main & Advanced Chemistry Hydrocarbons / हाइड्रोकार्बन Question Bank Alkyne

  • question_answer
    Shortest C-C bond length is present in [BVP 2004]

    A) \[C{{H}_{3}}-C{{H}_{2}}-C{{H}_{3}}\]

    B)  \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{3}}\]

    C) \[C{{H}_{2}}=CH-CH=C{{H}_{2}}\]

    D) \[CH\equiv C-C\equiv CH\]

    Correct Answer: D

    Solution :

               Bond length decrease with increase in Bond order. Hence triple bonded carbon has minimum bond length.                    \[C\text{ }\text{ }Cbond\text{ }length\text{ }=\text{ }1.54\text{ }{\AA}\]                    \[C\text{ }=\text{ }Cbond\text{ }length\text{ }=\text{ }1.33\text{ }{\AA}\] \[C~Cbond\text{ }length\text{ }=\text{ }1.22\text{ }{\AA}\]


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