JEE Main & Advanced Chemistry Hydrocarbons / हाइड्रोकार्बन Question Bank Alkene

  • question_answer
    Which one of the following characteristics apply to both ethene and ethyne [NCERT 1990]

    A) Explode when mixed with chlorine

    B) Decolourise Baeyer's reagent giving brown precipitate

    C) Rapidly absorbed by cold conc. \[{{H}_{2}}S{{O}_{4}}\]

    D) Form white precipitate with silver nitrate solution

    Correct Answer: B

    Solution :

      \[C{{H}_{2}}=C{{H}_{2}}+\underset{\text{alk}\text{.}}{\mathop{KMn{{O}_{4}}}}\,\underset{{{H}_{2}}O}{\mathop{\xrightarrow{[O]}}}\,\underset{OH}{\mathop{\underset{|\,\,\,\,\,\,}{\mathop{C{{H}_{2}}}}\,}}\,\underset{\text{Colour}\,\text{less}}{\mathop{-\underset{OH\,\,}{\mathop{\underset{|\,\,\,\,\,\,\,\,}{\mathop{C{{H}_{2}}\,}}\,}}\,+}}\,\underset{\begin{matrix}    \text{Brown}  \\    {}  \\ \end{matrix}}{\mathop{Mn{{O}_{2}}}}\,\] \[CH\equiv CH+\underset{alk.}{\mathop{KMn{{O}_{4}}}}\,\xrightarrow{[O]}\underset{\text{Oxalic acid}}{\mathop{\underset{COOH}{\mathop{\underset{|\,\,\,\,\,\,\,\,\,\,\,\,\,}{\mathop{COOH}}\,}}\,}}\,+\underset{\begin{matrix}    {}  \\    \text{Brown}  \\ \end{matrix}}{\mathop{Mn{{O}_{2}}}}\,\]


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