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question_answer1) Directions : (1 - 15) For question numbers 1-15, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices. Assertion : Cysteine can cross link peptide chains. Reason : Ammo acids are classified as essential and non-essential amino acids.
question_answer2) Assertion : Glucose and fructose give the same osazone. Reason : During osazone formation stereochemistry at \[{{C}_{1}}\] and \[{{C}_{2}}\] is destroyed.
question_answer3) Assertion : Valine is an essential amino acid. Reason: The lack of essential ammo acids in the diet causes Kwashiorkor.
question_answer4) Assertion : Disruption of the native structure of a protein is called denaturation. Reason : The change in colour and appearance of egg during cooking is due to denaturation.
question_answer5) Assertion : The specific rotation of a freshly prepared solution of a-glucose decreases from \[+112{}^\circ \] to \[52.7{}^\circ \] while that of (\[\beta \]-glucose increases from \[+\text{ }19{}^\circ \] to \[52.7{}^\circ \]. Reason : The change in specific rotation of an optically active compound with time to an equilibrium value is called mutarotation.
question_answer6) Assertion : Fructose reduces Fehling's solution and Tollens' reagent. Reason: Fructose does not contain any aldehyde group.
question_answer7) Assertion : DNA undergoes replication. Reason : DNA contains cytosine and thymine as pyrimidine bases.
question_answer8) Assertion : Amino acids are insoluble in benzene and ether. Reason : Amino acids exist as zwitter ions.
question_answer9) Assertion : Haemoglobin is a globular protein. Reason : Globular proteins are insoluble in water.
question_answer10) Assertion : Nucleotides are phosphate esters of nucleosides. Reason: The various nucleotides in nucleic acids are linked either through purine or pyrimidine bases.
question_answer11) Assertion : Solubility of proteins is minimum at the isoelectric point. Reason : At isoelectric point, protein molecule behaves as a zwitter ion.
question_answer12) Assertion : Alpha (\[\alpha \])-amino acids exist as internal salt in solution as they have amino and carboxylic acid groups in near vicinity. Reason : \[{{H}^{+}}\] ion given by carboxylic group \[\left( -COOH \right)\] is captured by amino group \[(-N{{H}_{2}})\] having lone pair of electrons.
question_answer13) Assertion : DNA has a double helix structure. Reason: The two strands in a DNA molecule are exactly similar.
question_answer14) Assertion : Glucose and fructose are reducing sugars. Reason : Glucose and fructose contain a free aldehydic and ketonic group adjacent to a \[>CHOH\]group respectively.
question_answer15) Assertion : Glucose when treated with \[C{{H}_{3}}OH\] in presence of dry HCl gas gives \[\alpha \]-and \[\beta \]-methyl glucosides. Reason : Glucose reacts with phenyl hydrazine to form crystalline osazone.
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