Answer:
In octahedral complex all the
ligands are lying along both the ends of all the three axes. In octahedral
complexes and orbitals
experience more repulsion as they point outward the axes along the direction of
the ligand.
In tetrahedral
complex. d-orbital splitting is inverted as compared to octahedral field
splitting because in tetrahedral complex non-axial orbitals are nearer to the
ligands than the axial orbitals.
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