Answer:
Di-tertiary butyl ketone \[{{(C{{H}_{3}})}_{3}}C-\overset{\begin{smallmatrix}
\text{O} \\
||
\end{smallmatrix}}{\mathop{C}}\,-C{{(C{{H}_{3}})}_{3}}\]
is a highly sterically hindered compound. The attack of\[HSO_{3}^{-}\]
(nucleophile) on the carbonyl group is not possible whereas it can readily take
place in acetone.
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