12th Class Chemistry The p-block Elements-II / p-ब्लॉक तत्व-II Question Bank 11th CBSE Chemistry The P-Block Elements

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    \[C{{O}_{2}}\] is a gas while \[Si{{O}_{2}}\] is a solid. Explain.

    Answer:

                    Carbon because of its small size and higher electro negativity than silicon forms \[p\pi -p\pi \] double bonds with O-atoms to form \[C{{O}_{2}}\] molecule. These molecules of \[C{{O}_{2}}\] are held together by weak van der Waals forces of attraction which can be easily overcome by collisions of the molecules at room temperature. Consequently,\[C{{O}_{2}}\] is a gas. Silicon, on the other hand, because of its bigger size and lower electro negativity than carbon has little tendency to form\[p\pi -p\pi \] double bonds with O-atoms. Instead, each silicon atom forms four single covalent bonds with O-atoms which are tetrahedrally arranged around it leading to the formation of a three-dimensional network structure (Fig. 11.18, page 11/40). To break these covalent bonds, a large amount of energy is needed and hence \[Si{{O}_{2}}\] is a high melting solid.


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