Answer:
Electronic configuration of V (Z = 23) is [Ar]18 3d3 4s2
\[\therefore \] V (IV) is \[{{[Ar]}^{18}}\,3{{d}^{1}}\] and V (V) is \[{{[Ar]}^{18}}3{{d}^{0}}\]
As V (IV) has one unpaired electron, therefore, it is paramagnetic.
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