11th Class Chemistry Organic Chemistry: Some Basic Principles & Techniques / कार्बनिक रसायन : कुछ मूलभूत सिद्धांत एवं तकन Question Bank 11th CBSE Chemistry Organic Chemistry: Some Basic Principles & Techniques

  • question_answer
    Explain the following: (i) exists in keto form but  exists in enol form. (ii) \[C{{H}_{2}}=C{{H}^{-}}\]is a better nucleophile than \[HC\equiv {{C}^{-}}\].

    Answer:

                    (i)                 Enol form \[(II)\] is not stabilized and hence it exists in the keto form \[(I)\] Enol form (IV) is stabilized by resonance energy \[(150.6\,kJ\,mo{{l}^{-1}})\] of the benzene ring and hence \[(III)\] exists in the enol form (IV) (ii) In \[{{H}_{2}}C=C{{H}^{-}},\] the carbon atom carrying the -ve charge is \[s{{p}^{2}}\]-hybridized while in \[HC\equiv {{C}^{-}},\] the carbon atom carrying the -ve charge is sp-hybridized. Since a \[s{{p}^{2}}\]-hybridized carbon is less electronegative than a sp-hybridized carbon, therefore, \[{{H}_{2}}C=C{{H}^{-}}\]is a better nucleophile than \[HC\equiv {{C}^{-}}\].


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