11th Class Chemistry Hydrocarbons / हाइड्रोकार्बन Question Bank 11th CBSE Chemistry Hydrocarbons

  • question_answer
    An alkene has molecular mass 70. Write all the possible structural isomers and give their IUPAC names.

    Answer:

                    The general formula of alkene \[={{C}_{n}}{{H}_{2n}}\] \[\therefore \] \[12\times n+1\times 2n=70,\] or \[14n=70\]  or\[n=70/14\,=5\]. The molecular formula of alkene is \[{{C}_{5}}{{H}_{10}}\]. The possible structural isomers are: (i) \[\underset{\text{Pent-1-ene}}{\mathop{\overset{5}{\mathop{C}}\,{{H}_{3}}-\overset{4}{\mathop{C}}\,{{H}_{2}}-\overset{3}{\mathop{C}}\,{{H}_{2}}-\overset{2}{\mathop{C}}\,H=\overset{1}{\mathop{C}}\,{{H}_{2}}}}\,\] (ii) \[\underset{\text{Pent-2-ene}}{\mathop{\overset{5}{\mathop{C}}\,{{H}_{3}}-\overset{4}{\mathop{C}}\,{{H}_{2}}-\overset{3}{\mathop{C}}\,H=\overset{2}{\mathop{C}}\,H-\overset{1}{\mathop{C}}\,{{H}_{3}}}}\,\] (iii)\[\underset{\begin{smallmatrix}   \\  \text{3-Methylbut-1-ene} \end{smallmatrix}}{\mathop{\overset{4}{\mathop{C}}\,{{H}_{3}}-\overset{3}{\mathop{\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,}}\,H-\overset{2}{\mathop{C}}\,H=\overset{1}{\mathop{C}}\,{{H}_{2}}}}\,\] (iv)\[\underset{\text{2-Methylbut-1-ene}}{\mathop{\overset{1}{\mathop{C}}\,{{H}_{2}}=\overset{2}{\mathop{\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,}}\,-\overset{3}{\mathop{C}}\,{{H}_{2}}-\overset{4}{\mathop{C}}\,{{H}_{3}}}}\,\] (v)\[\underset{\begin{smallmatrix}   \\  \text{2-Methyl}\,\text{but-2-ene} \end{smallmatrix}}{\mathop{\overset{1}{\mathop{C}}\,{{H}_{3}}-\overset{2}{\mathop{\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C}}\,}}\,=\overset{3}{\mathop{C}}\,H-\overset{4}{\mathop{C}}\,{{H}_{3}}}}\,\]


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