JEE Main & Advanced Chemistry Thermodynamics / रासायनिक उष्मागतिकी First Law Of Thermodynamics

First Law Of Thermodynamics

Category : JEE Main & Advanced

Helmholtz and Robert Mayer proposed first law of thermodynamics. This law is also known as law of conservation of energy. It states that,

“Energy can neither be created nor destroyed although it can be converted from one form into another.”

\[{{E}_{2}}-{{E}_{1}}=\]\[\Delta E\,=q+w\]

i.e. (Change in internal energy) = (Heat added to the system) +(Work done on the system)

If a system does work (w) on the surroundings, its internal energy decreases. In this case,  \[\Delta E=q+(-w)=q-w\]

i.e.(Change in internal energy)=(Heat added to the system) – (work done by the system)

The relationship between internal energy, work and heat is a mathematical statement of first law of thermodynamics.         

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