Answer:
\[w=2.303nRT\,log\left(
\frac{{{V}_{2}}}{{{V}_{1}}} \right)\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,......(i)\]
\[PV=nRT\,\,\,\,\,\,\,\,\,\,\,......(ii)\]
From eqs. (i) and
(ii)
\[w=2.303PV\,\log
\left( \frac{{{V}_{2}}}{{{V}_{1}}} \right)\]
\[=2.303\times
1\times 10\log \left( \frac{10}{2} \right)\]
\[=16.1litre-atm=16.1\times
101.3J=1630.93J\]
\[{{w}_{\exp
}}=-1630.93J\]
\[q=-{{w}_{\exp
}}=1630.93J\]
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