11th Class Chemistry Organic Chemistry: Some Basic Principles & Techniques / कार्बनिक रसायन : कुछ मूलभूत सिद्धांत एवं तकन

  • question_answer 36)
    What are electrophiles and nucleophiles? Explain with examples.

    Answer:

    (i) Nucleus loving groups are called nucleophiles. They are negatively charged or electron rich species. Examples: Negatively Charged Nucleophile Electron Rich Nucleophile \[C{{l}^{-}},B{{r}^{-}},{{I}^{-}},\overset{-}{\mathop{C}}\,N\] \[{{H}_{2}}\overset{\centerdot \centerdot }{\mathop{O_{\centerdot }^{\centerdot }}}\,,{{H}_{2}}\overset{\centerdot \centerdot }{\mathop{S_{\centerdot }^{\centerdot }}}\,\] \[O{{H}^{-}},NH_{2}^{-},S{{H}^{-}},{{O}^{2-}}\] \[{{S}^{2-}}\]etc. \[\overset{\centerdot \centerdot }{\mathop{N{{H}_{3}}}}\,,R-\overset{\centerdot \centerdot }{\mathop{N{{H}_{2}}}}\,\]   \[R-\underset{\centerdot \centerdot }{\overset{\centerdot \centerdot }{\mathop{O}}}\,-H,R-\underset{\centerdot \centerdot }{\overset{\centerdot \centerdot }{\mathop{O}}}\,-R\]   (ii) Electron loving groups are called electrophiles. They are either positively charged or electron deficient neutral molecules. Examples : Positively Charged Electrophiles Electron Deficient Neutral Electrophiles \[{{R}^{+}},\overset{+}{\mathop{RCO}}\,,C{{l}^{+}},B{{r}^{+}},{{I}^{+}}NO_{2}^{+}\] \[S{{O}_{3}},B{{F}_{3}},AlC{{l}_{3}}\] (anhydrous) \[FeC{{l}_{3}},\]  


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