11th Class Chemistry Organic Chemistry: Some Basic Principles & Techniques / कार्बनिक रसायन : कुछ मूलभूत सिद्धांत एवं तकन

  • question_answer 109)
      Give three points of differences between inductive effect and resonance effect.

    Answer:

       
    Inductive Effect Resonance Effect
    (i) Involves displacement of sigma electrons and hence occurs only in saturated compounds. (i) Involves delocalisation of \[\pi \]-electrons and lone pair and hence occurs in unsaturated compounds and conjugated systems.
    (ii) Electro negativity difference induces this effect towards the more electro -ve atom to give partial +ve or -ve charges. (ii) It takes place due to interaction between two \[\pi \]-bonds or a \[\pi \]-bond and a lone pair of electron.
    (iii) Inductive effects are transmitted over short distances in saturated carbon chains and the magnitude of the effect decreases rapidly as the distance from the halogen atom (source) increases. \[\begin{align}   & C\to -\overset{\delta \delta {{\delta }^{+}}}{\mathop{C}}\,\to -\overset{\delta {{\delta }^{+}}}{\mathop{C}}\,\to -\overset{{{\delta }^{+}}}{\mathop{C}}\, \\  & \to -C{{l}^{{{\delta }^{-}}}} \\ \end{align}\] (iii) The resonance effects are transmitted all along the length in the conjugated system. The electron pair is completely transferred to give positive and negative charges.
     


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